New solar fuel machine 'mimics plant life'

[Demobe Profile]

A prototype solar device has been unveiled which mimics plant life, turning the Sun's energy into fuel.

The machine uses the Sun's rays and a metal oxide called ceria to break down carbon dioxide or water into fuels which can be stored and transported.

Conventional photovoltaic panels must use the electricity they generate in situ, and cannot deliver power at night.

Details are published in the journal Science.

The prototype, which was devised by researchers in the US and Switzerland, uses a quartz window and cavity to concentrate sunlight into a cylinder lined with cerium oxide, also known as ceria.

Ceria has a natural propensity to exhale oxygen as it heats up and inhale it as it cools down.

If as in the prototype, carbon dioxide and/or water are pumped into the vessel, the ceria will rapidly strip the oxygen from them as it cools, creating hydrogen and/or carbon monoxide.

Hydrogen produced could be used to fuel hydrogen fuel cells in cars, for example, while a combination of hydrogen and carbon monoxide can be used to create "syngas" for fuel.

It is this harnessing of ceria's properties in the solar reactor which represents the major breakthrough, say the inventors of the device. They also say the metal is readily available, being the most abundant of the "rare-earth" metals.

Methane can be produced using the same machine, they say.
Refinements needed

The prototype is grossly inefficient, the fuel created harnessing only between 0.7% and 0.8% of the solar energy taken into the vessel.

Most of the energy is lost through heat loss through the reactor's wall or through the re-radiation of sunlight back through the device's aperture.

But the researchers are confident that efficiency rates of up to 19% can be achieved through better insulation and smaller apertures. Such efficiency rates, they say, could make for a viable commercial device.

"The chemistry of the material is really well suited to this process," says Professor Sossina Haile of the California Institute of Technology (Caltech). "This is the first demonstration of doing the full shebang, running it under (light) photons in a reactor."

She says the reactor could be used to create transportation fuels or be adopted in large-scale energy plants, where solar-sourced power could be available throughout the day and night.

However, she admits the fate of this and other devices in development is tied to whether states adopt a low-carbon policy.

"It's very much tied to policy. If we had a carbon policy, something like this would move forward a lot more quickly," she told the BBC.

It has been suggested that the device mimics plants, which also use carbon dioxide, water and sunlight to create energy as part of the process of photosynthesis. But Professor Haile thinks the analogy is over-simplistic.

"Yes, the reactor takes in sunlight, we take in carbon dioxide and water and we produce a chemical compound, so in the most generic sense there are these similarities, but I think that's pretty much where the analogy ends."

http://www.bbc.co.uk/news/science-environment-12051167